Data analysis and determination of the electrochemical parameters of ECrev mechanism via new convolutive voltammetry and digital simulation methods

I.S.El-Hallag

Abstract

A simple and accurate method for data analysis and evaluating the relevant chemical and electrochemical parameters (homogeneous chemical rate constant kc, the equilibrium constant K, the diffusion coefficient D,and the standard reduction potential E0 ) of the ECrev mechanism were done using new convolutive voltammetry and digital simulationmethods. The experimental data were combined with digital simulation to ascertain the nature of electrode reaction as well as the verification of the electrochemical parameters estimated experimentally.