Geochemical provenance and spatial distribution of fluoride in Groundwater in parts of Raniganj coal field, West Bengal, India

S. Gupta, D. Mondal, A. Bardha

Abstract

Present research work undertakes the hydro-geochemical characterization as well as demarcation of fluoride (F-) contaminated area by means of GIS modeling. F- concentration in the study area ranges from 0.20 mg/l to 1.67 mg/l with a mean of 0.72 mg/l. Among the twenty six (26) collected samples from water table sedimentary aquifer of study area 54% samples have F- concentration <0.6 mg/l; and 8% of the samples have concentration >1.5 thereby unsuitable for drinking purpose. Majority of the water samples fall under the category of Ca-Mg-Cl followed by Ca-HCO3 type hydrofacies. Fluoride has a significant (p<.05) positive correlation with bicarbonate (HCO3 -) ion and it also shows a positive correlation with sodium (Na+) but higher negative correlation with calcium (Ca2+). This may be attributed to ion-exchange process where Ca2+ ions in water may react with clay minerals (sodiummontmorillonite) to release Na+ ion in groundwater. All the groundwater samples have Ca2+<

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