Hydrogen Storage in a Crosslinked Phloroglucinol-Terephthalaldehyde Framework with Exposed Iron Sites

Kapil Pareek, Rupesh Rohan

Abstract

Hydrogen adsorption has been studied in a cross-linked polymeric complex with coordinatively unsaturated iron metals. The complex displays hydrogen storage capacity up to 1.3 wt% at 298 K and 100 atm with an isosteric heat of adsorption up to 11.5 kJ mol-1.