Kinetics and Mechanism of Oxidation of Allyl Alcohol in Perchloric Acid Medium by Waugh-Type Enneamolybdomanganate(IV)

Babasaheb D Bhosale

Abstract

Two-electron transfer complimentary reaction between Waugh type enneamolybdomanganate(IV) and allyl alcohol is investigated in perchloric acid medium. The reaction is first order with respect to both the reactant and the order with respect to H+ ion is 1.45. The activation parameters were also determined and a possible complimentary two electron transfer mechanism is suggested for the reaction between allyl alcohol and Waugh-Type Enneamolybdomanganate(IV)