Synthesis and Spectroscopic Characterization of Complexes of 2-Aminothiophenol with Tetrachlorides of Metals

R. N. Pandey and Satyendra Sha

Abstract

The synthesis, characterization and structural elucidation of some bis-chelates of composition [MCl2(ATP)2] (M = Ti (IV), Zr (IV), Pd (IV), Pt (IV) and Sn (IV); ATP = Deprotonated 2-aminothiophenol bidentate anion) are reported. The octahedral structure of metal chelates are deduced by elemental analysis, magnetic susceptibility measurements, IR, far-IR, UV-vis, and 1 H NMR spectral data.