Synthesis and Spectroscopic Properties of Some Hydridophosphine Complexes of Iridium (III)

R. N. Pandey and Satyendra Sha

Abstract

Mononuclear hydridophosphine complexes of iridium (III) are prepared and characterized by elemental analyses, conductance, magnetic, IR, UV-vis and 1 H NMR spectral data. All complexes are found octahedral and two phosphine ligands are at trans-disposition. The ligand field bands are obscured in some cases. However, electronic spectral data is consistent with assigned structure.