SynthesisAnd Investigation Of The Properties Of L-Tris (Parabenzylidene amino phenyl) PhosphiteAnd ItsMetalCarbonylDerivatives

Akbar Raissi Shabari, Joseph J

Abstract

The synthesis and investigation of the properties of the Schiff base tris(parabenzylideneaminophenyl) phosphite as well as the preparation in solution at atmospheric pressure(under N2) of this compounds as a ligand (L) with some metal carbonyls(mononuclear) having the general formula shown below are described. M(CO)n-x Lx,M=Ni(0),n=4,x=1,2, M=Fe(0),n=5,x=1, M=Cr(0), n=6, x=1 L=(C6H5-CH=N-C6H4-O)3P. Elemental analysis as well as infrared, ultraviolet-visible and NMR spectroscopic data are also presented.