Thermal Decomposition Studies on Iron(III) Complexes of 1,2-Bis(imino-4’-antipyrinyl) ethane with Varying Counter Ions

Nayathuparambil Thomas Madh

Abstract

Phenomenological and mechanistic characteristics of the thermal decomposition of perchlorate, nitrate, thiocyanate, chloride and bromide iron(III) complexes with the Schiff base 1,2-bis(imino-4’- antipyrinyl)ethane (GA) were studied by thermo gravimetric and derivative thermo gravimetric analyses. It was observed that the counter anions may have a major effect on the thermal stability of the present complexes.The decomposition reaction mechanism is in accordance with a ‘random nucleation with one nucleus on each particle, i.e. the Mampel model’.